Researchers discover source for generating 'green' electricity
June 22, 2011University of Minnesota engineering researchers in the College of Science and Engineering have recently discovered a new alloy material that converts heat directly into electricity. This revolutionary energy conversion method is in the early stages of development, but it could have wide-sweeping impact on creating environmentally friendly electricity from waste heat sources.
Researchers say the material could potentially be used to capture waste heat from a car's exhaust that would heat the material and produce electricity for charging the battery in a hybrid car. Other possible future uses include capturing rejected heat from industrial and power plants or temperature differences in the ocean to create electricity. The research team is looking into possible commercialization of the technology.
"This research is very promising because it presents an entirely new method for energy conversion that's never been done before," said University of Minnesota aerospace engineering and mechanics professor Richard James, who led the research team."It's also the ultimate 'green' way to create electricity because it uses waste heat to create electricity with no carbon dioxide."
To create the material, the research team combined elements at the atomic level to create a new multiferroic alloy, Ni45Co5Mn40Sn10. Multiferroic materials combine unusual elastic, magnetic and electric properties. The alloy Ni45Co5Mn40Sn10 achieves multiferroism by undergoing a highly reversible phase transformation where one solid turns into another solid. During this phase transformation the alloy undergoes changes in its magnetic properties that are exploited in the energy conversion device.
During a small-scale demonstration in a University of Minnesota lab, the new material created by the researchers begins as a non-magnetic material, then suddenly becomes strongly magnetic when the temperature is raised a small amount. When this happens, the material absorbs heat and spontaneously produces electricity in a surrounding coil. Some of this heat energy is lost in a process called hysteresis. A critical discovery of the team is a systematic way to minimize hysteresis in phase transformations. The team's research was recently published in the first issue of the new scientific journal Advanced Energy Materials.
This video is not supported by your browser at this time.
Watch a short research video of the new material suddenly become magnetic when heated.
In addition to Professor James, other members of the research team include University of Minnesota aerospace engineering and mechanics post-doctoral researchers Vijay Srivastava and Kanwal Bhatti, and Ph.D. student Yintao Song. The team is also working with University of Minnesota chemical engineering and materials science professor Christopher Leighton to create a thin film of the material that could be used, for example, to convert some of the waste heat from computers into electricity."This research crosses all boundaries of science and engineering," James said. "It includes engineering, physics, materials, chemistry, mathematics and more. It has required all of us within the university's College of Science and Engineering to work together to think in new ways."
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Jun 22, 2011
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Jun 22, 2011
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If it were 100% efficient then, yes, it would be a perpetual motion machine but then we wouldn't be able to extract any work from it, thereby making it fairly useless
Jun 22, 2011
Rank: 4.7 / 5 (6)
No, this is not a perpetual motion machine, it's a method of capturing heat that would otherwise be lost to the environment and transforming it back into a usable form.
So, if you have an 50% efficient engine that is taking in 10 watts worth of fuel and outputting 5 watts of usable energy, it is then losing 5 watts of energy as heat. If you wrapped your engine in this material and its efficiency was 50% then you would be able to capture 2.5 watts of that lost heat and use it as electricity. You still have 10 watts in and 10 watts out, you've just changed how efficient your system is.
Hysteresis means that the system's output is dependent on its internal states in addition to its inputs. The article is unclear on the details, but basically by minimizing the impact that hysteresis on the system they are able to increase its efficiency. Think of hysteresis in this case as internal drag. If you minimize it, you get more power out of the system.
Jun 22, 2011
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Jun 22, 2011
Rank: 4.5 / 5 (2)
They misspoke when saying "direct transfer of heat into energy". As usual, they still need to have temperature gradient for this to work, because they need to have heating / cooling cycle for the device to work continuously.
Here is from their abstract:
Theory predicts that under optimal conditions the performance compares favorably with the best thermoelectrics. Because of the low hysteresis of the alloy, a promising area of application of this concept appears to be energy conversion at small T, suggesting a possible route to the conversion of the vast amounts of energy stored on earth at small temperature difference.
Jun 22, 2011
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Jun 22, 2011
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Jun 22, 2011
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Jun 22, 2011
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Jun 22, 2011
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Some materials can be used as "heat pumps" and work in the opposite way: using electricity to push heat in a direction opposite to what it normally would.
This particular material is interesting for only two reasons: it is more efficient and it becomes magnetic while being used. The magnetism may be the more useful of the two...
Jun 22, 2011
Rank: 4 / 5 (1)
In theory, yes, although traditionally these "heat to energy" devices produce very little energy. Even if you paint one side black, metal tends to reach equilibrium with itself very quickly, hence the reason you don't touch the kettle while the burner is on. You'd be much better off using traditional solar energy.
Jun 22, 2011
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Jun 22, 2011
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Jun 22, 2011
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Jun 22, 2011
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Jun 22, 2011
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Jun 22, 2011
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Jun 22, 2011
Rank: 5 / 5 (1)
So you need 'optimal' conditions to match 'favorably' with existing thermoelectrics. Which means, efficiency is still very low and also that its use will remain limited to niche applications.
Jun 22, 2011
Rank: 1 / 5 (1)
it looks like a copper plate what they are heating it with.
it might as well be acting like a capacitor.
Jun 23, 2011
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BTW if any of you guys feel strongly about entropy, google 'fluctuation theorem'. There is always the possibility of entropy decreasing.
Jun 23, 2011
Rank: 5 / 5 (1)