Researchers heat up gold to surprising effect: It gets harder not softer

January 22, 2009 Researchers heat up gold to surprising effect: It gets harder not softer

Enlarge

Common sense tells us that when you heat something up it gets softer, but a team of researchers, led by University of Toronto chemistry and physics professor R.J. Dwayne Miller, has demonstrated the exact opposite. Their findings will be published online in the prestigious international journal Science on January 22.

"It is counter-intuitive but the gold got harder instead of softer," says Miller. Can you imagine a blacksmith heating up gold to pound it thinner, only to find it got harder? But we heated the gold at terrific heating rates - greater than 1 billion million degrees per second - that approach the temperature of the interior of stars."

The gold was heated at rates too fast for the electrons absorbing the light energy to collide with surrounding atoms and lose energy," he explains. "This means the electrons are on average further away from the atomic nucleus and there is less screening of the positive nuclear charge by these heated electrons. The bonds between atoms actually got stronger.

"A gold crystal consists of gold ions and weakly bound electrons which screen the repulsive forces between the ions," explains lead author Ralph Ernstorfer, a former postdoctoral research fellow with Prof. Miller, who is now at the Max-Planck Institute for Quantum Optics in Garching and the TU Munich, Germany. As a result, there are attractive forces between ions. In contrast to many other materials, heating the electrons in gold with an ultrashort laser pulse makes the forces between the ions stronger, resulting in a harder lattice with an increased melting point.

"The effect of bond hardening in gold has been theoretically predicted. Now we have actually observed it for the first time," says Ernstorfer.

Researchers heat up gold to surprising effect: It gets harder not softer
Enlarge


The researchers employed a technique called 'femtosecond electron diffraction' to make the observation. This technique can be described as a camera for making atomic-level movies. By sending femtosecond pulses of electrons through the thin gold crystal, the atomic motions of the ions were recorded in real time while heating the material with lasers. By measuring the speed of heating, amplitude of the atomic motions, and ultimate melting of the crystal, the laser-induced change of the lattice stability could be inferred.

"We now have an atomic-level view of this rarified state of matter, referred to as warm dense matter, and can relate the observed liquid structure to the increased lattice stability," says Miller.

Source: University of Toronto


print this article email this article download pdf blog this article bookmark this article     Stumble it Digg this share on Facebook retweet share on Reddit add to delicious
Rate this story - 4 /5 (5 votes)

Rank Filter

Move the slider to adjust rank threshold, so that you can hide some of the comments.


Display comments: newest first

  • Alizee - Jan 22, 2009
    • Rank: 3.8 / 5 (4)
    Can you imagine a blacksmith heating up gold to pound it thinner, only to find it got harder
    Not at all - but I can imagine, huge pressure of electrons makes material more dense and stiff. For example, NIF is used to study materials of 300 g/cm3 in density and temperatures between 100 and 200 electronvolts.

    https://www.llnl..../Ng.html

    I dunno, how both these effects can be separated easily to provoke such surprising article name. Isn't it rather just another attempt for artificial sensation?
  • KBK - Jan 28, 2009
    • Rank: 1 / 5 (1)
    Gold is UNIQUE in the periodic table as having only ONE isotope that is stable. utterly unique.

    Alchemists utilized chemical (pH) and heat/distillation/vapour/condensing/etc methods of creating nano-materials and to get access to cooper paired gold molecules, for room temperature superconductors and for the physical ingestion of these gold nano-particles that have been 'charged' (prepared) (ie, inter-metallic bonds broken and then held in a specific way) to the right level.This flows into the natural superconducting inter-dimensional characteristic of the human nervous system as outlined by the Offices of the US Naval Academy of Research, in some of their more interesting studies. Yes, the 'philosopher's stone'. Designed for human ingestion.

    Look up the Antikythera Mechanism.

    It is a similar situation here. The alchemists are still a few thousand years ahead of what 'modern science' is doing in these realms. In the science and the social, cultural, ethical, and psychological developments attached to such understandings.

    There are levels of existence and awareness and then.... some folks just can't cross some those barriers.

    Don't get angry with me if you have a lack of understanding of what I just wrote. After all, I'm being frank. The problem is in you, not me.

    All I wrote, is a thing called 'esoteric sign' that allows those without bias to search deeper and farther than those who do have the bias. If you have the bias, you won't look, you are not ready. Simple enough!

    'nuff said.


January 22, 2009 all stories

Comments: 2

4 /5 (5 votes)
  • Stumble this up

  • Digg this

  • share this

  • hide
  • Related Stories

  • Smart drug delivery system -- Gold nanocage covered with polymer (w/ Video)
    created Nov 01, 2009 | popularity not rated yet | comments 0
  • High in Sodium: Highly Charged Tungsten Ions May Diagnose Fusion Energy Reactors
    created Sep 08, 2009 | popularity not rated yet | comments 0
  • Graphene's versatility promises new applications
    created Jul 09, 2009 | popularity not rated yet | comments 0
  • Virus battery could power cars, electronic devices
    created Apr 02, 2009 | popularity not rated yet | comments 0
  • Turning sunlight into liquid fuels (Video)
    created Mar 11, 2009 | popularity not rated yet | comments 0



  • hide
  • Relevant PhysicsForums posts

Other News

Stars Fueled by Dark Matter Could Hold Secrets to the Universe

Stars Fueled by Dark Matter Could Hold Secrets to the Universe

Physics / General Physics

created Nov 03, 2009 | popularity 4.5 / 5 (50) | comments 41

(PhysOrg.com) -- The first stars in the universe may have been very different from the stars we see today, yet they may hold clues to understanding some of the mysterious features of the universe. These "dark ...


Second Law of Thermodynamics May Explain Economic Evolution

Second Law of Thermodynamics May Explain Economic Evolution

Physics / General Physics

created Nov 02, 2009 | popularity 4.3 / 5 (30) | comments 28

(PhysOrg.com) -- Terms such as the "invisible hand," laissez-faire policy, and free-market principles suggest that economic growth and decline in capitalist societies seem to be somehow self-regulated. Now, ...


High-performance plasmas may make reliable, efficient fusion power a reality

High-performance plasmas may make reliable, efficient fusion power a reality

Physics / Plasma Physics

created Nov 02, 2009 | popularity 4.7 / 5 (39) | comments 31

In the quest to produce nuclear fusion energy, researchers from the DIII-D National Fusion Facility have recently confirmed long-standing theoretical predictions that performance, efficiency and reliability ...


'Teapot effect' solved

Solving Teapot Effect

Physics / General Physics

created Nov 02, 2009 | popularity 4.9 / 5 (11) | comments 10

(PhysOrg.com) -- A team of scientists from France have worked out why teapots dribble at low flow rates, and how to stop them. The effect is called the "teapot effect", and solving it could finally put an ...


Laser accelerated protons to the highest energies so far

Researchers use trident laser to accelerate protons to record energies

Physics / General Physics

created Nov 02, 2009 | popularity 4.7 / 5 (6) | comments 10

An international team of physicists at Los Alamos National Laboratory has succeeded in using intense laser light to accelerate protons to energies never before achieved. Using this technique, scientists can ...