Researchers heat up gold to surprising effect: It gets harder not softer

January 22, 2009 Researchers heat up gold to surprising effect: It gets harder not softer

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Common sense tells us that when you heat something up it gets softer, but a team of researchers, led by University of Toronto chemistry and physics professor R.J. Dwayne Miller, has demonstrated the exact opposite. Their findings will be published online in the prestigious international journal Science on January 22.

"It is counter-intuitive but the gold got harder instead of softer," says Miller. Can you imagine a blacksmith heating up gold to pound it thinner, only to find it got harder? But we heated the gold at terrific heating rates - greater than 1 billion million degrees per second - that approach the temperature of the interior of stars."

The gold was heated at rates too fast for the electrons absorbing the light energy to collide with surrounding atoms and lose energy," he explains. "This means the electrons are on average further away from the atomic nucleus and there is less screening of the positive nuclear charge by these heated electrons. The bonds between atoms actually got stronger.

"A gold crystal consists of gold ions and weakly bound electrons which screen the repulsive forces between the ions," explains lead author Ralph Ernstorfer, a former postdoctoral research fellow with Prof. Miller, who is now at the Max-Planck Institute for Quantum Optics in Garching and the TU Munich, Germany. As a result, there are attractive forces between ions. In contrast to many other materials, heating the electrons in gold with an ultrashort laser pulse makes the forces between the ions stronger, resulting in a harder lattice with an increased melting point.

"The effect of bond hardening in gold has been theoretically predicted. Now we have actually observed it for the first time," says Ernstorfer.

Researchers heat up gold to surprising effect: It gets harder not softer
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The researchers employed a technique called 'femtosecond electron diffraction' to make the observation. This technique can be described as a camera for making atomic-level movies. By sending femtosecond pulses of electrons through the thin gold crystal, the atomic motions of the ions were recorded in real time while heating the material with lasers. By measuring the speed of heating, amplitude of the atomic motions, and ultimate melting of the crystal, the laser-induced change of the lattice stability could be inferred.

"We now have an atomic-level view of this rarified state of matter, referred to as warm dense matter, and can relate the observed liquid structure to the increased lattice stability," says Miller.

Source: University of Toronto


   
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  • Alizee - Jan 22, 2009
    • Rank: 3.8 / 5 (4)
    Can you imagine a blacksmith heating up gold to pound it thinner, only to find it got harder
    Not at all - but I can imagine, huge pressure of electrons makes material more dense and stiff. For example, NIF is used to study materials of 300 g/cm3 in density and temperatures between 100 and 200 electronvolts.

    https://www.llnl..../Ng.html

    I dunno, how both these effects can be separated easily to provoke such surprising article name. Isn't it rather just another attempt for artificial sensation?
  • KBK - Jan 28, 2009
    • Rank: 1 / 5 (1)
    Gold is UNIQUE in the periodic table as having only ONE isotope that is stable. utterly unique.

    Alchemists utilized chemical (pH) and heat/distillation/vapour/condensing/etc methods of creating nano-materials and to get access to cooper paired gold molecules, for room temperature superconductors and for the physical ingestion of these gold nano-particles that have been 'charged' (prepared) (ie, inter-metallic bonds broken and then held in a specific way) to the right level.This flows into the natural superconducting inter-dimensional characteristic of the human nervous system as outlined by the Offices of the US Naval Academy of Research, in some of their more interesting studies. Yes, the 'philosopher's stone'. Designed for human ingestion.

    Look up the Antikythera Mechanism.

    It is a similar situation here. The alchemists are still a few thousand years ahead of what 'modern science' is doing in these realms. In the science and the social, cultural, ethical, and psychological developments attached to such understandings.

    There are levels of existence and awareness and then.... some folks just can't cross some those barriers.

    Don't get angry with me if you have a lack of understanding of what I just wrote. After all, I'm being frank. The problem is in you, not me.

    All I wrote, is a thing called 'esoteric sign' that allows those without bias to search deeper and farther than those who do have the bias. If you have the bias, you won't look, you are not ready. Simple enough!

    'nuff said.


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