Graphene makes light work of aircraft design
June 8, 2010
(PhysOrg.com) -- Faster and lighter aircraft could be built using an incredible super-thin material just one atom thick, according to new research conducted at The University of Manchester.
Writing in the journal Advanced Materials, a team of materials scientists and physicists say graphene has the potential to replace carbon fibres in high performance materials that are used to build aircraft.
Graphene - discovered in 2004 by physicists Prof Andre Geim and Dr Kostya Novoselov at The University of Manchester - is a two-dimensional layer of carbon atoms that resembles chicken wire.
As well as being an excellent conductor of electrons, with the potential to replace silicon, graphene is also one of the stiffest-known materials. A recent study found it to be the strongest material ever measured.
This led researchers to investigate its behaviour and properties when mixed with other materials.
A University of Manchester team, which included Dr Novoselov, put a single graphene sheet between two layers of polymer and used a technique called Raman spectroscopy to measure how the carbon bonds responded when the graphene was stretched.
Raman spectroscopy works by shining a laser light onto a molecule and then collecting and analysing the wavelength and intensity of the resulting scattered light.
The technique basically measures bond vibration between atoms. As researchers stretch the bond the vibration changes frequency. It can be compared to tuning a guitar string and hearing the pitch change.
Researchers were able to use Raman spectroscopy to look at the change of the vibrational energy of the bond and then worked out the change in bond length. From this information they calculated the improvement in stiffness the graphene gave to the polymer composite.
Professor Robert Young of the School of Materials, said: “We have found the theories developed for large materials still hold even when a material is just one atom thick.”
“We can now start to use the decades of research into traditional carbon fibre composites to design the next generation of graphene-based materials.”
Dr Ian Kinloch, a researcher in the School of Materials, commented: “This relatively new material continues to amaze, and its incredible properties could be used to make structural, lightweight components for fuel efficient vehicles and aircraft.”
More information: ‘Interfacial Stress Transfer in a Graphene Monolayer Nanocomposite,’ L. Gong, I. A. Kinloch, R. J. Young, I. Riaz, R. Jalil and K. S. Novoselov, Advanced Materials.
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Jun 08, 2010
Rank: 1.7 / 5 (6)
What in an airplane could be built one atom thick only by using graphene? I am sure it is not the main structure.
Jun 08, 2010
Rank: 3 / 5 (1)
If this formula is as general and accurate as this article suggests, the potential is huge.
Jun 08, 2010
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Jun 08, 2010
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Jun 08, 2010
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Jun 08, 2010
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Jun 08, 2010
Rank: 4 / 5 (3)
If you wanted to create so-called sigma-bonds (which are the bonds within the plane of graphene) between 2 adjacent layers, you would almost certainly alter the geometry and no longer have graphene - you'd probably get diamond.
Each of the layers has a delocalized structure of electrons 'floating' above/below the plane of the bonds. These are the electrons which are so mobile when we speak of graphene as a near-ideal conductor. If we were to somehow force these electrons to form stronger bonds than the intrinsically weak bonding normally seen between graphene layers, it is likely that we would lose most if not all of the useful electronic properties.
Jun 08, 2010
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Jun 09, 2010
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Jun 09, 2010
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What can't graphene 'do'?
Jun 09, 2010
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The new Boeing 787 will be the true test of whether or not composites in their current form are really a viable option. Hopefully graphene becomes economical enough to solve some of these problems
Jun 09, 2010
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I think we can start using it in the place of the carbon nanotubes.
Jun 09, 2010
Rank: 5 / 5 (1)
Yes, all bonds between atoms are ultimately mediated by electric charge (and to a vastly lesser extent, gravity.) However, you'd get an 'F' on any chemistry test if you said that the two atoms in an O2 molecule are bonded electrostatically.
Jun 09, 2010
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There's no abuse of language here. In physics, electrostatic interactions are interactions between electrically charged particles that are not due to the motion of the particles. Just because electrons are shared doesn't mean the bond's force isn't completely due to electrostatic interactions - it is. The charge distribution is, of course, changed due to the quantum nature of electrons, but this simply serves to put an extra constraint on the lowest electrostatic configuration.
If anything, chemists abuse terminology by saying that a covalent bond is formed via the sharing of AN electron. BULL CRAP! Bonded atoms share ENERGY LEVELS that are occupied by a superposition of ALL of the electrons present.
Jun 09, 2010
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And before you lunge once again into "ENERGY LEVELS", as a supposed physics cognoscenti I expect you to at least be aware of the concept of orbitals and their spatial-geometric relationship to the respective nucleus.
Jun 09, 2010
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Jun 09, 2010
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Look, there is both a quantitative and qualitative gulf, in order of escalating bond strength, between Wan der Walls adhesion, ionic bonding, and covalent bonding.
Yes, all of these effects can be traced to arrangements of electrons in shells around nuclei. However, the mechanisms of these effects are different.
In Van der Waals adhesion, electron clouds become lopsided, creating attractive dipole moments between otherwise neutral atoms. These dipole moments lead to adhesion, which is relatively weak.
In ionic bonds, you have literal charged particles -- atoms differing by at least 2 electron charges -- being electrostatically attracted to each other WITHOUT sharing their electrons.
In covalent bonds, electrons are commingled among the bonded nuclei, and such bonds are the strongest of all.
Jun 09, 2010
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Jun 11, 2010
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Jun 11, 2010
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http://www.physor...014.html
Jun 12, 2010
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I realize in the picture representation of graphene it is more about showing the basic structure of the bonds in the sheets, rather than actual "to scale" relationships between carbon atoms and the spaces involved.
So what I would wonder is, in the space inside a single "hex ring" of graphene, how much of that space is "empty" and how much is occupied by electrons? Is there enough space to make a CHAIN of graphene molecules interlocking physically, rather than chemically, like links of a metallic chain? If so, problem solved.
That is, if the Graphene is "chicken wire" then simply cross another "wire"(graphene molecule or polymer,) through the space between the carbon atoms.
If this pictoral representation is severely flawed and the carbon atoms are crammed much closer, then of course this idea wouldn't work, unless you could insert defects into the graphene such that a 6-atom hex is missing to allow threading orthogonal chains of graphene .
Jun 12, 2010
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I know you're gonna laugh, but "Houston Dome".
Jun 12, 2010
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there are a number of ways to dope graphene sheets- perhaps this could be a way of constructing 3d lattice:
http://www.columb...tion.pdf
Jun 12, 2010
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What are you talking about?
"The majority of the structural composites in the F-35 are made out of bismaleimide (BMI) and composite epoxy material."
http://www.reinfo...n-award/
http://www.scaled.com/
Jun 12, 2010
Rank: 3 / 5 (2)
I can forsee carbon being harvested from industrial processes- maybe even chimneys, fer cripe's- and metals being repurposed for those essential functions that the carbon materials( I want to call the class "CARBONITE", cause I like the way it sounds) are unable to perform.
This would solve a number of difficulties at one blow -heck, it might even usher in a new Golden Age.
Jun 14, 2010
Rank: 5 / 5 (1)
http://en.wikiped...arbonite