For the First Time Ever, Scientists Watch an Atom's Electrons Moving in Real Time
August 4, 2010 by Paul Preuss
A classical diagram of a krypton atom (background) shows its 36 electrons arranged in shells. Researchers have measured oscillations of quantum states (foreground) in the outer orbitals of an ionized krypton atom, oscillations that drive electron motion. Credit: courtesy Lawrence Berkeley National Laboratory
(PhysOrg.com) -- An international team of scientists led by groups from the Max Planck Institute of Quantum Optics (MPQ) in Garching, Germany, and from the U.S. Department of Energy's Lawrence Berkeley National Laboratory and the University of California at Berkeley has used ultrashort flashes of laser light to directly observe the movement of an atom's outer electrons for the first time.
Through a process called attosecond absorption spectroscopy, researchers were able to time the oscillations between simultaneously produced quantum states of valence electrons with great precision. These oscillations drive electron motion.
"With a simple system of krypton atoms, we demonstrated, for the first time, that we can measure transient absorption dynamics with attosecond pulses," says Stephen Leone of Berkeley Lab's Chemical Sciences Division, who is also a professor of chemistry and physics at UC Berkeley. "This revealed details of a type of electronic motion - coherent superposition - that can control properties in many systems."
Leone says an example of the importance of coherent dynamics is its crucial role in photosynthesis, citing recent work by the Graham Fleming group at Berkeley. "The method developed by our team for exploring coherent dynamics has never before been available to researchers. It's truly general and can be applied to attosecond electronic dynamics problems in the physics and chemistry of liquids, solids, biological systems, everything."
The team's demonstration of attosecond absorption spectroscopy began by first ionizing krypton atoms, removing one or more outer valence electrons with pulses of near-infrared laser light that were typically measured on timescales of a few femtoseconds (a femtosecond is 10^-15 second, a quadrillionth of a second). Then, with far shorter pulses of extreme ultraviolet light on the 100-attosecond timescale (an attosecond is 10^-18 second, a quintillionth of a second), they were able to precisely measure the effects on the valence electrons.
The results of the pioneering measurements performed at MPQ by the Leone and Krausz groups and their colleagues are reported in the August 5 issue of the journal Nature.
Parsing the fine points of valence electron motion
Valence electrons control how atoms bond with other atoms to form molecules or crystal structures, and how these bonds break and reform during chemical reactions. Changes in molecular structures occur on the scale of many femtoseconds and have often been observed with femtosecond spectroscopy, in which both Leone and Krausz are pioneers.
In krypton's single ionization state, quantum oscillations in the valence shell cycled in a little over six femtoseconds. Attosecond pulses probed the details (black dots), filling the gap in the outer orbital with an electron from an inner orbital, and sensing the changing degrees of coherence between the two quantum states thus formed (below). Credit: Courtesy Lawrence Berkeley National Laboratory
Zhi-Heng Loh of Leone's group at Berkeley Lab and UC Berkeley worked with Eleftherios Goulielmakis of Krausz's group to perform the experiments at MPQ. By firing a femtosecond pulse of infrared laser light through a chamber filled with krypton gas, atoms in the path of the beam were ionized by the loss of one to three valence electrons from their outermost shells.The experimenters separately generated extreme-ultraviolet attosecond pulses (using the technique called "high harmonic generation") and sent the beam of attosecond probe pulses through the krypton gas on the same path as the near-infrared pump pulses.
By varying the time delay between the pump pulse and the probe pulse, the researchers found that subsequent states of increasing ionization were being produced at regular intervals, which turned out to be approximately equal to the time for a half cycle of the pump pulse. (The pulse is only a few cycles long; the time from crest to crest is a full cycle, and from crest to trough is a half cycle.)
"The femtosecond pulse produces a strong electromagnetic field, and ionization takes place with every half cycle of the pulse," Leone says. "Therefore little bursts of ions are coming out every half cycle."
Although expected from theory, these isolated bursts were not resolved in the experiment. The attosecond pulses, however, could precisely measure the production of the ionization, because ionization - the removal of one or more electrons - leaves gaps or "holes," unfilled orbitals that the ultrashort pulses can probe.
Femtosecond-scale pulses were fired to ionize krypton atoms (wide beam). Separately created attosecond-scale pulses (narrow beam) were absorbed by the krypton atoms. Spectroscopy mapped the precise timing of the oscillation between quantum states thus created. Credit: Courtesy Lawrence Berkeley National Laboratory
The attosecond pulses do so by exciting electrons from lower energy orbitals to fill the gap in krypton's outermost orbital - a direct result of the absorption of the transient attosecond pulses by the atoms. After the "long" femtosecond pump pulse liberates an electron from the outermost orbital (designated 4p), the short probe pulse boosts an electron from an inner orbital (designated 3d), leaving behind a hole in that orbital while sensing the dynamics of the outermost orbital.In singly charged krypton ions, two electronic states are formed. A wave-packet of electronic motion is observed between these two states, indicating that the ionization process forms the two states in what's known as quantum coherence.
Says Leone, "There is a continual 'orbital flopping' between the two states, which interfere with each other. A high degree of interference is called coherence." Thus when the attosecond probe pulse clocks the outer valence orbitals, it is really clocking the high degree of coherence in the orbital motion caused by ionization.
Indispensable attosecond pulses
"When the bursts of ions are made quickly enough, with just a few cycles of the ionization pulse, we observe a high degree of coherence," Leone says. "Theoretically, however, with longer ionization pulses the production of the ions gets out of phase with the period of the electron wave-packet motion, as our work showed."
So after just a few cycles of the pump pulse, the coherence is washed out. Thus, says Leone, "Without very short, attosecond-scale probe pulses, we could not have measured the degree of coherence that resulted from ionization."
The physical demonstration of attosecond transient absorption by the combined efforts of the Leone and Krausz groups and their colleagues will, in Leone's words, "allow us to unravel processes within and among atoms, molecules, and crystals on the electronic timescale" - processes that previously could only be hinted at with studies on the comparatively languorous femtosecond timescale.
More information: "Real-time observation of valence electron motion," by Eleftherios Goulielmakis, Zhi-Heng Loh, Adrian Wirth, Robin Santra, Nina Rohringer, Vladislav Yakovlev, Sergey Zherebtsov, Thomas Pfeifer, Abdallah Azzeer, Matthias Kling, Stephen Leone, and Ferenc Krausz, appears in the 5 August 2010 issue of the journal Nature.
Provided by Lawrence Berkeley National Laboratory (news : web)
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Aug 04, 2010
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Aug 04, 2010
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Aug 04, 2010
Rank: 5 / 5 (1)
Wattson: The "recording" is of course slowed down for human observation. We can observe the electron several times during the same period. Meaning we can follow it as it oscillates live and inconsistent, instead of merely calculating an average. Hence the illustration.
Aug 04, 2010
Rank: 5 / 5 (2)
Aug 04, 2010
Rank: not rated yet
What I don't understand is how half of a cycle can cause ionization? Is 1/2 a photon causing this ionization?
Aug 04, 2010
Rank: 5 / 5 (3)
Aug 04, 2010
Rank: 5 / 5 (2)
Same question. I presume Heisenberg's Uncertainty Principle is still valid 'cause you need to ionize the atom in order to "observe" the electrons. The principle applies if electrons are observed in its fundamental state, and not in transitions between states?
Aug 05, 2010
Rank: 3.3 / 5 (3)
abzu :That was what I was thinking when I first saw the headline link. However they are observing the electrons so that should make them behave as if they were particles and not as waves. That is they are testing for the position of the electrons and not the momentum of the electrons. As pointed out in the article the results were as expected by theory.
Ethelred
Aug 05, 2010
Rank: 2 / 5 (1)
Aug 05, 2010
Rank: not rated yet
From what I read, I don't think that the title is very correct. They didn't measure motion but ionization rates and coherences degrees. Which of course imply motion, but then, with electrons what doesn't...
Aug 06, 2010
Rank: 3.7 / 5 (3)
It wasn't in real time. It was in pulses. Each pulse would collapse any waveform. They did not see individual electrons. They saw SOME electrons in SOME atoms, SOME of the time.
Rarely if ever did they see the same electron two pulses in a row.
Ethelred
Aug 06, 2010
Rank: 5 / 5 (1)
Real time is pulses, as governed by quantum mechanics.
Once you launch a photon at an electron you change its state. Thus what you see is only a snapshot of what it was before you changed it. You can never know what the product of your interaction became until you probe it again -- at which point you face the same paradox. Heisenberg's uncertainty principle is so simple that it describes the paradox of any type of interaction/observation in all possible universes where energy cannot be lost or created, but rather transformed -- such as ours (if the former is even conceptually possible.)
Aug 06, 2010
Rank: 1.5 / 5 (2)
Secondly, Heisenberg Uncertainty does not apply to monochromatic light, in any regard. See: http://blog.hassl...n_a.html
Aug 06, 2010
Rank: 3 / 5 (2)
Maybe if they can manage it with a Plank interval. How it could be done is another thing as light just won't do that.
What paradox? It does describe the interactions but not the paradox of the interactions since there is no paradox.
Ethelred
Aug 07, 2010
Rank: 3.7 / 5 (3)
http://nobelprize...es/1989/
Ions, being heavier than electrons can have a more precise measurement of their position and momentum. More precise being the key as an electron can have both its momentum and position measured at the same time. However the more precise the measurement of one property is the less precise the other property can be measured. For instance if you trap an electron with, oh say lasers, and cut its velocity to millimeters per second then its position becomes vague. Every test has had this result. Or worse if the test is badly done.
Ethelred
Aug 07, 2010
Rank: 1 / 5 (2)
In short > "Quantum Coherence" = "MAGNETIC CURRENTS"
Aug 07, 2010
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Aug 08, 2010
Rank: 3.5 / 5 (2)
This statement wants to dogmatically deny the entire of the Dehmelt Nobel Prize, which demonstrated simultaneous measurement of the momentum and the position, of both electrons and ions, contrary to the "uncertainty principle" which is merely an abstract mathematical theory, not a physical fact. Uncertainty is not based on empirical observation, which observations denies "uncertainty" per Dehmelt, and per the proof regarding monochromatic photons in the reference cited.
Clinging to the "known" does not a good scientist make. Exploring beyond the "known" is what makes a good scientist.
Aug 09, 2010
Rank: 3.7 / 5 (3)
Nothing he did was contrary to the uncertainty principle. It is that simple and is in no dogmatic. Its a simple fact. YOU are the making the claim NOT Dehmelt. At no time did I deny his work. Just your FALSE claims about it.Which fits every experiment. Including Dehmelt's.Clinging to false interpretation of someone else's work who DOES NOT agree with your claims is a sign of a crank.
YOU made the claim now post link or something to support your claim. I posted the stuff you misunderstood and that supported me and the Uncertainty Principle. It is funny how Demelt DID NOT make the claim you did.
Ethelred
Aug 13, 2010
Rank: 3.5 / 5 (2)
E.G., the only limitation to accuracy of position is the time of emission accuracy which is related to the accuracy of the timer. NASA has developed a timer system accurate to 10 femtoseconds, with projections of improvements into the .001 femtosecond regime. Emission time is then not an issue over a pre-measured course and thus location of the photon is known to within the accuracy limits of the timer.
We can know momentum with absolute certainty because the momentum of a photon is directly related to its frequency.
Aug 14, 2010
Rank: 3 / 5 (2)
NO. You can't know the position.
Explanation follows
Aug 14, 2010
Rank: 3.7 / 5 (3)
Just claiming that you can do something doesn't mean you can and in this instance you don't even understand that 'coherent' entails entanglement.Doesn't matter for TWO reasons. ONE the photons are entangled or they are not coherent. TWO 10 femtoseconds is precision but is in no way complete certainty. Which is what you claimed. Same for attoseconds only you get more precision but you still get entanglement and a lack of simultaneous MEASUREMENT. You CAN predict, but not measure, to attosecond accuracy. Which simply isn't complete certainty.
Yes there is more.
Aug 14, 2010
Rank: 3 / 5 (2)
And next time you post a link you might try to actually give a clue as to where the heck the information is if the link is so vastly less specific than your thought experiment.
Ethelred
Aug 14, 2010
Rank: 3.5 / 5 (2)
Labeling anything that disagrees with "standard" concepts as "crank" or "crackpot" makes you appear the same way as a dogmatic religious fanatic. Science is not a religion. Is is a search for observable facts.
Aug 15, 2010
Rank: 3 / 5 (2)
Since the photons are entangled you cannot measure a single photon. Thus you cannot know the phase.Less. Due to entanglement.Then you didn't measure a single photon or even a coherent packet.No. They have different masses and thus are different. Not counting spin.And with different masses which is what Heisenberg was dealing with.
Aug 15, 2010
Rank: 3.7 / 5 (3)
A claim you have failed to show any support for and I showed the problems with your claims. However if you can show that someone has actually has done the experiment and gotten the claimed results then I will be willing to change my mind. So far all I have your unsupported claims. Even your link had nothing to support your claims. Nor did Dehmel ever say anything that supports you. I asked for evidence and you have only given me YOU. You don't seem to have done the experiments either. Just made the claims.
Aug 15, 2010
Rank: 3.7 / 5 (3)
Ethelred
Aug 15, 2010
Rank: 1 / 5 (1)
Heisenberg uncertainty does not apply to LASER optics. That is physical fact, not theory.
Aug 15, 2010
Rank: 1 / 5 (1)
Abstract: Measurement of the polarisation properties of light (polarimetry) is a powerful diagnostic tool with uses in many applications including ellipsometry. The horizontally and vertically polarized components of light scattered from depolarising surfaces were independently measured by a two-channel coherent laser radar. Because of the phase-sensitive nature of heterodyne detection, the relative phase of these components can be measured, and this gives all the information required to construct the polarization ellipse at any instant. The phenomenon of laser speckle ensures that the intensity and polarization state fluctuate as the beam scans across the surface of the target. The method described allows the time development of the polarization state to be followed in real time.
Aug 15, 2010
Rank: 1 / 5 (1)
Institute of Atmospheric Optics RAS
"...optical wave propagation in the atmosphere, calculating the parameters of optical waves propagating in both inhomogeneous layers and random-inhomogeneous stratified media under the conditions of thermal blooming."
Aug 15, 2010
Rank: 5 / 5 (1)
The title "Continuous Creation, Einstein and the 'Expanding' Big-Bang Universe" is followed by another text titled "Toward an Empirical Reality in Consciousness Studies". Excerpt:And:And:And a lot more of the same quality ...
Aug 15, 2010
Rank: not rated yet
Aug 15, 2010
Rank: 5 / 5 (1)
But no, you cannot measure the exact position and the exact momentum of a single photon simultaneously.
Aug 15, 2010
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Aug 15, 2010
Rank: 1 / 5 (1)
Since you asked, the prefix "mono" means "one" or "single". The word "chromatic" is an optical physics term relating to the color or colors of light. Thus, the term "monochromatic" simply means, only one color, which then means only one frequency of E/M propagation. When that light is also "coherent" (all photons perfectly in-phase)it takes on many properties that normal white light does not have, such as predictability, which predictability is used in countless laser optics systems throughout the world, to accomplish amazingly accurate measurements of diverse physical objects and events. I gave some examples earlier.
Aug 16, 2010
Rank: 1 / 5 (1)
frajo and ethelred (probably the same person) should take up the argument with the international team of scientists led by groups from the Max Planck Institute of Quantum Optics (MPQ) in Garching, Germany, and from the U.S. Department of Energy's Lawrence Berkeley National Laboratory and the University of California at Berkeley.
I'm sure they won't have the courage to argue with all those people, telling them that their experimental results are IMPOSSIBLE according to the theory called "heisenberg uncertainty".
The empirical facts always win out over theories, no matter how mathematically attractive or believible those theories might be.
Aug 16, 2010
Rank: 5 / 5 (2)
Yes there is more. I pity little minds that mistake brevity for wit
Aug 16, 2010
Rank: 5 / 5 (2)
You don't seem to get this at all. There are NO INDIVIDUAL photons in a coherent beam. They are all smeared together thus you can't measure one photon. You are measuring a BEAM.[Heisenberg uncertainty does not apply to LASER optics. That is physical fact, not theory. This is a misunderstanding on your part not fact. BEAMS are not PHOTONS. Does THAT get through?
More clarifying thoughts to follow
Aug 16, 2010
Rank: 5 / 5 (2)
Again. A coherent monochromatic beam IS NOT a single photon. It is a collection of photons that are smeared out via entanglement. Thus while you can measure the beam you can't measure the photons that make up the beam because they don't really exist as individual photons under those conditions. And no that is not the same as randomness.
And I might add that I got some of these ways of thinking from Dr. Prins who is fighting against the physics establishment. I am not sure that I fully agree with him but some of the concepts are very useful to me in thinking about uncertainty and entanglement.
Ethelred
Aug 16, 2010
Rank: 5 / 5 (2)
But that post was mostly garbage based unfounded speculation about what others understand. And what you actually were doing when you used laser range finding.Close. Add in a vacuum and avoid some cosmological speculation about VERY early in the history of the Universe and you have it.But we haven't measured even one photon and thus are still not dealing with Heisenberg's Uncertainty Principle. In other words you made claims that had nothing to with what you thought you were claiming.
Dennis Moore
Aug 16, 2010
Rank: 5 / 5 (2)
I had a feeling what at least part of you misunderstanding was when you said:Extra More
Aug 16, 2010
Rank: 5 / 5 (2)
Those electrons had their positions measured but not their momenta. You can't get both at once with high precision. And they didn't.
Some More
Aug 16, 2010
Rank: 5 / 5 (2)
Remember that was what you were talking about. NOT beams. And remember that you have been unable to find a single reference of Dehmelt claiming he did what you claim he did. Or anyone else for that matter.
More later or was that litter
Aug 16, 2010
Rank: 5 / 5 (2)
However perhaps I missed something. Perhaps all the science magazines missed it too. Perhaps every paper on the planet missed it. Perhaps YOU could link to it. You know, an experiment where someone, anyone measured an electon's position and momentum simultaneously to a precision higher than the Uncertainty Principle allows.
Just a touch more
Aug 16, 2010
Rank: 5 / 5 (2)
Ethelred
Aug 16, 2010
Rank: 5 / 5 (1)
One more point. I may be wrong (and will be grateful when corrected), but I don't think that coherence is the same as entanglement. Coherent light is simply a beam of light of in-step waves of identical frequency, phase, and polarization. No quantum considerations needed here.
Aug 18, 2010
Rank: 1 / 5 (1)
Secondly, a beam of laser light is made of photons. Arguments which are trying to distinguish photons from considerations such as ray-tracing demonstrate a lack of understanding of foundational principles of optical physics and quantum physics.
Arguments that the photons have not been measured in these circumstances are also based purely in ignorance of laser optics.
Why don't you take your arguments up with the experimenters referenced in the article, as I suggested earlier? They will probably have more patience with your ignorance than I do.
Aug 18, 2010
Rank: 5 / 5 (2)
So quit evading and show something that backed you. You claimed that Dehmel did it. WHERE did he say he did it?
I have asked that question MANY times and you have ignored EVERY time.
More to come
Aug 18, 2010
Rank: 5 / 5 (2)
Not beams of photons being predicted or even measured. But a single photon or entangled pair of photons being MEASURED.
More about photons not beams
Aug 18, 2010
Rank: 5 / 5 (2)
I notice when people evade I and I point it out. I also notice when it done multiple times as you have been doing.
Answer the bloody questions and quit insulting people instead.
Ethelred