Image: As depth increases inside the Earth, so does the pressure and heat. The experiments conducted by Carnegie researchers on magnesiowüstite mimicked pressures of the lower mantle--between 500,000 and 1 million times the pressure at sea level. Under those conditions, the electrons of iron in the mineral were forced to pair-up in orbits, which changed the elasticity of the magnesiowüstite. This change may be the reason why seismic waves behave so peculiarly at those depths.( Image courtesy S. Jacobsen, M. Wysession, and G. Caras.)

“Until this research, scientists have simplified the effects of iron on mantle materials. It is the most abundant transition metal in the planet and our results are not what scientists have predicted,” he continued. “We may have to reconsider what we think is going in that hidden zone. It’s much more complex than we imagined.”

The crushing pressures in the lower mantle squeeze atoms and electrons so closely together that they interact differently from under normal conditions, even forcing spinning electrons to pair up in orbits. In theory, seismic-wave behavior at those depths may result from the vice-gripping pressure effect on the electron spin-state of iron in lower-mantle materials. Lin’s team performed ultra high-pressure experiments on the most abundant oxide material there, magnesiowüstite (Mg,Fe)O, and found that the changing electron spin states of iron in that mineral drastically affect the elastic properties of magnesiowüstite. The research may explain the complex seismic wave anomalies observed in the lowermost mantle.

As co-author of the study Viktor Struzhkin elaborated: “This is the first study to demonstrate experimentally that the elasticity of magnesiowüstite significantly changes under lower-mantle pressures ranging from over 500,000 to 1 million times the pressure at sea level (1 atmosphere). Magnesiowüstite, containing 20% iron oxide and 80% magnesium oxide, is believed to constitute roughly 20% of the lower mantle by volume. We found that when subjected to pressures between 530,000 and 660,000 atmospheres the iron’s electron spins went from a high-spin state (unpaired) to a low-spin state (spin-paired). While monitoring the spin-state of iron, we also measured the rate-of-change in the volume (density) of magnesiowüstite through the electronic transition. That information enabled us to determine how seismic velocities will vary across the transition.”

“Surprisingly, bulk seismic waves travel about 15% faster once the electrons of iron are spin-paired in the magnesium-iron oxide,” commented co-author Steven Jacobsen. “The measured velocity jump across the transition might, therefore, be detectable seismically in the deep mantle.” The experiments were conducted inside a diamond-anvil pressure cell using the intense X-ray light source at the nation's third-generation synchrotron source, Argonne National Laboratory near Chicago.

“The mysterious lower mantle region can’t be sampled directly. So we have to rely on experimentation and theory. Since what happens in Earth’s interior affects the dynamics of the entire planet, it’s important for us to find out what is causing the unusual behavior of seismic waves in that region,” stated Lin. “Up to now, earth scientists have understood Earth’s interior by only considering pure oxides and silicates. Our results simply point out that iron, the most abundant transition metal throughout the entire Earth, gives rise to very complex properties in that deep region. We look forward to our next experiments to see if we can refine our understanding of what is happening there,” he concluded.

Source: Carnegie Institution of Washington