Image: Here, a soliton (blob with red and blue stripes) moves along a conducting polymer chain (aqua and yellow for hydrogen and carbon). The soliton blob causes a localized bend in the chain. The traditional way to make polymer actuate is to dope the material with an ion such as sodium, represented by the red dot. Image courtesy / Yip lab

Currently, robotic muscles move 100 times slower than ours. But engineers using the Yip lab's new theory could boost those speeds - making robotic muscles 1,000 times faster than human muscles - with virtually no extra energy demands and the added bonus of a simpler design. This study appears in the Nov. 4 issue of the journal Physical Review Letters.

In this case, a robotic muscle refers to a device that can be activated to perform a task, like a sprinkler activated by pulling a fire alarm lever, explains Yip, a professor of nuclear engineering and materials science and engineering.

In the past few years, engineers have made the artificial muscles that actuate, or drive, robotic devices from conjugated polymers. "Conjugated polymers are also called conducting polymers because they can carry an electric current, just like a metal wire," says Xi Lin, a postdoctoral associate in Yip's lab. (Conventional polymers like rubber and plastic are insulators and do not conduct electricity.)

Conjugated polymers can actuate on command if charges can be sent to specific locations in the polymer chain in the form of "solitons" (charge density waves). A soliton, short for solitary wave, is "like an ocean wave that can travel long distances without breaking up," Yip adds. (See figures.) Solitons are highly mobile charge carriers that exist because of the special nature (the one-dimensional chain character) of the polymer.

Image: New MIT research has suggested another way to make polymer actuate, shown here. The new method is to shine light of a specific frequency (hn), on the conducting polymer. The polymer in this image is a chain (neutral charge, green) that is naturally curved before exposure. The effect of light (hn frequency) is to create positive charges (red) in a localized area. The positive charges enhance the chemical bonding between the polymer’s units and straighten out the curved chain in that area. (This straightening occurs where the red and blue striped lobe appeared in image above. The lobe can move along the polymer chain rapidly.)

Scientists already knew that solitons enabled the conducting polymers to conduct electricity. Lin's work attempts to explain how these materials can activate devices. This study is useful because until now, scientists, hampered by not knowing the mechanism, have been making conducting polymers in a roundabout way, by bathing (doping) the materials with ions that expand the volume of the polymer. That expansion was thought to give the polymers their strength, but it also makes them heavy and slow.

Lin discovered that adding the ions is unnecessary, because theoretically, shining a light of a particular frequency on the conducting polymer can activate the soliton. Without the extra weight of the added ions, the polymers could bend and flex much more quickly. And that rapid-fire motion gives rise to the high-speed actuation, that is, the ability to activate a device.

To arrive at these conclusions, Lin worked from fundamental principles to understand the physical mechanisms governing conjugated polymers, rather than using experimental data to develop hypotheses about how they worked. He started with Schrödinger's equation, a hallmark of quantum mechanics that describes how a single electron behaves (its wave function). But solving the problem of how a long chain of electrons behaves was another matter, requiring long and complex analyses.

This research was funded by Honda R&D Co. and the Defense Advanced Research Projects Agency/Office of Naval Research. Yip and Lin's collaborators on the work are Professor Ju Li at Ohio State University and Professor Elisabeth Smela at the University of Maryland.

Source: MIT