Liquid CO2 drives rapid thrust of diamond-bearing structures

Freeze-dried ice cream looks like the original product, and even tastes pretty good, but "drying" ice cream at room temperature would leave a sour-smelling, sloppy mess. Similarly, diamonds ejected from deep in the Earth can survive the journey intact only if they head toward the surface quickly and under just the right conditions.

Diamonds, found almost exclusively within kimberlite formations, are stable at great depth and at the planet's surface but rapidly turn to graphite under the high temperature/low pressure condi-tions of most eruptions. A new integrated theory of kimberlite formation, published in the May 3 issue of the journal Nature, invokes a leading wedge of fluid carbon dioxide, combined with catastrophic cooling upon reaching the Earth's surface, to explain how the diamonds survive as magma powers them upward.

"As long as they're hot, you want them to stay at high pressure," said Lionel Wilson, a professor of volcanology at the University of Lancaster and co-author of the Nature paper, "and then if you're going to decompress them, you've got to get them cold really fast."

Wilson and James Head, a professor of planetary geology at Brown University, developed the theory while searching for a solution to the problem of how round glass droplets might be formed on the moon where there is no atmosphere and little gravity to shape them. As the scien-tists talked over one proposed mechanism, recalls Head, they each thought: "hmm, that could explain how kimberlites form."

"We had tried to understand how you get this glass that comes out of eruptions on the moon," said Head, "The chemistry we saw seemed to require low pressures at great depth, which is kind of an oxymoron. We realized the molten rock comes up in a crack and when the crack opens, there is a small zone of very low pressure."

A handful of nagging questions have challenged geologists trying to explain the genesis of car-rot-shaped kimberlite formations. The diamonds are one problem. The shape is another. The in-verted cone of a kimberlite is filled with cracked and broken chunks of solidified magma, mixed with glass globules and some diamonds, all confined in a narrow, underground space, not scat-tered across the landscape as they would be in a normal volcanic explosion.

Geologists find little evidence for flowing lava around the formations, suggesting that the erup-tion is suddenly capped or stoppered. Also, glass globules, like those moon artifacts that Head and Wilson were trying to explain, appear throughout the formation and it's not at all clear how they could be formed underground.

In the mechanism that Wilson and Head suggest, a wedge of liquid carbon dioxide forms above a source of carbon dioxide-rich magma at a depth of about 250 km. As the wedge drives upward, it fractures the rock it passes through, dropping fragments into the tube of magma beneath it.

Streaming upward at speeds of about 108-180 kilometers per hour, the underlying magma resup-plies the carbon dioxide in the tip chamber. The balance between the overlying carbon dioxide and the excess dissolved in the magma maintains an equilibrium pressure at the tip of about 70 MPa during ascent, driving this rock-busting locomotive upward. As carbon dioxide bubbles out of the magma, a layer of foam forms on top – ultimately the source of the unexplained glass spheres.

When the tip of the carbon dioxide chamber breaks the surface, the fluid rapidly expands to be-come a gas, sending a jet of carbon dioxide, magma foam, and rock fragments shooting into the air at speeds of up to 5000 km per hour, typical of a booster rocket or a jet engine. A cavity three kilometers deep might empty in only about ten seconds. This rapid expansion flash-freezes the magma near the surface and sends shock waves through the cavity, imploding the cavity walls and filling the chamber with rubble.

Pressure builds once again in the mostly-sealed chamber and waves of expansion and compres-sion bounce up and down the chamber, cooling and shattering magma, breaking up the surround-ing rock, spattering magma droplets into glassy spheres and sorting and rearranging the resulting fragments. The rapid chilling soon seals off the magma supply completely, ending the process. The whole progression likely takes less than an hour.

One implication of the new theory is that surface geologic conditions have little to do with where kimberlites form – and thus where diamonds are deposited. Unlike some recent theories of kim-berlite formation, no source of underground water is needed to drive the explosive power of the formation. If the theory proves true, it would suggest that diamonds have been found in South Africa or on the Canadian Shield mainly because that's where people have looked for them and that a concerted search could turn up kimberlites – and the associated diamonds -- anywhere.

Source: Brown University